Orochi Warriors
- Bonus characters
- Successfully complete the indicated task to unlock the corresponding character:
- Azai Nagamasa: Successfully complete Wei Story mode Stage 6.
- Cao Cao: Successfully complete Wei Story mode Stage 7.
- Da Ji: Successfully complete all stages in the game, including the Gaiden stages.
- Da Qiao: In Wu Story mode Gaiden 5, meet Da Qiao before the enemy does.
- Dian Wei: Successfully complete Wei Story mode Stage 7.
- Fuuma Kotaro: In Wu Story mode Gaiden 2, defeat him after all supply troops have reached your HQ.
- Gan Ning: Successfully complete Wei Story mode Stage 6.
- Guan Ping: Successfully complete Sengoku Story mode Stage 1.
- Guan Yu: Successfully complete Shu Story mode Stage 7.
- Honda Tadakatsu: Impress him in all Story modes in Gaiden 7.
- Huang Gai: Successfully complete Wei Story mode Stage 5.
- Huang Zhong: Successfully complete Sengoku Story mode Stage 1.
- Imagawa Yoshimoto: In Wei Story mode Gaiden 4, prevent all ploy troops from entering the village.
- Inahime: Successfully complete Wu Story mode Stage 5.
- Ishida Mitsunari: Successfully complete Wei Story mode Stage 2.
- Jiang Wei: In Shu Story mode Gaiden 2, succeed in initiating Jiang Wei's ambush plan.
- Kunoichi: In Wu Story mode Gaiden 4, successfully escort all peasants.
- Ling Tong: Successfully complete Sengoku Story mode Stage 5.
- Liu Bei: Successfully complete Shu Story mode Stage 8.
- Lu Bu: Impress Lu Bu by defeating him in all Story modes Gaiden 8.
- Lu Meng: Successfully complete Wu Story mode Stage 3.
- Lu Xun: In Sengoku Story mode Gaiden 3, successfully escort Lu Xun to your HQ.
- Ma Chao: In Sengoku Story mode Gaiden 2, make sure that all peasants escape and Ma Chao survives.
- Meng Huo: Successfully complete Shu Story mode Stage 4.
- Miyamoto Musashi: In Shu Story mode Gaiden 6, successfully open the dam and keep all the yellow swordsmen alive.
- Mori Ranmaru: Successfully complete Wu Story mode Stage 1.
- Naoe Kanetsugu: Successfully complete Sengoku Story mode Stage 7.
- Nene: In Wei Story mode Gaiden 3, defeat the two Nene clones within 4 minutes after their appearances.
- Oichi: Successfully complete Wei Story mode Stage 6.
- Okuni: Successfully complete Sengoku Story mode Stage 3.
- Orochi: Unlock all characters besides Orochi.
- Pang Tong: Successfully complete Wei Story mode Stage 4.
- Saika Magoichi: Successfully complete Shu Story mode Stage 2.
- Sanada Yukimura: Successfully complete Shu Story mode Stage 3.
- Shima Sakon: Successfully complete Wu Story mode Stage 3.
- Sima Yi: In Sengoku Story mode Gaiden 6, foil Sima Yi's strategy by killing the two retreating Orochi generals.
- Sun Jian: Successfully complete Wu Story mode Stage 7.
- Sun Quan: Successfully complete Wu Story mode Stage 7.
- Sun Shang Xiang: Successfully complete Wu Story mode Stage 5.
- Tachibana Ginchiyo: Successfully complete Shu Story mode Stage 1.
- Taishi Ci: Successfully complete Wu Story mode Stage 2.
- Takeda Shingen: Successfully complete Sengoku Story mode Stage 7.
- Uesugi Kenshin: Successfully complete Sengoku Story mode Stage 7.
- Wei Yan: Successfully complete Shu Story mode Stage 3.
- Xiahou Dun: Successfully complete Wei Story mode Stage 4.
- Xiahou Yuan: Successfully complete Wei Story mode Stage 4.
- Xiao Qiao: Successfully complete Wu Story mode Stage 3.
- Xu Zhu: Successfully complete Wei Story mode Stage 1.
- Yuan Shao: Successfully complete Shu Story mode Stage 5.
- Yue Ying: Successfully complete Shu Story mode Stage 2.
- Zhang Fei: Successfully complete Shu Story mode Stage 7.
- Zhang He: In Wei Story - Gaiden 2, successfully rescue Zhang He and defend the HQ.
- Zhang Jiao: Successfully complete Sengoku Story mode Stage 3.
- Zhou Tai: Successfully complete Wu Story mode Stage 6.
- Zhou Yu: Successfully complete Wu Story mode Stage 1.
- Zhu Rong: Successfully complete Shu Story mode Stage 4.
- Zhuge Liang: Successfully complete Shu Story mode Stage 7.
- Zuo Ci: Finish all four Story modes.